翻訳と辞書 Words near each other ・ Triphenylene ・ Triphenylmethane ・ Triphenylmethanol ・ Triphenylmethyl chloride ・ Triphenylmethyl hexafluorophosphate ・ Triphenylmethyl radical ・ Triphenylphosphine ・ Triphenylphosphine dichloride ・ Triphenylphosphine oxide ・ Triphenylphosphine selenide ・ Triphenylphosphine sulfide ・ Triphenylstibine ・ Triphenylsulfonium triflate ・ Triphenyltin chloride ・ Triphenyltin compounds ・ Triphenyltin hydride ・ Triphenyltin hydroxide ・ Triphon Silyanovski ・ Triphone ・ Triphora ・ Triphora (gastropod) ・ Triphora (orchid) ・ Triphora trianthophora ・ Triphoreae ・ Triphoridae ・ Triphorinae ・ Triphoroidea ・ Triphos ・ Triphosa ・ Triphosa dubitata Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Triphenyltin hydride ： ウィキペディア英語版 Triphenyltin hydride |Section2= |Section7= |Section8= }} Triphenyltin hydride is the organotin compound with the formula (C6H5)3SnH. It is a white distillable oil that is soluble in organic solvents. It is often used as a source of "H·" to generate radicals or cleave carbon-oxygen bonds. ==Preparation and reactions== Ph3SnH, as it is more commonly abbreviated, is prepared by treatment of triphenyltin chloride with lithium aluminium hydride.〔Clive, D. L. J. "Triphenylstannane" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. 〕 Although Ph3SnH is treated as a source of "H·", in fact it does not release free hydrogen atoms, which are extremely reactive species. Instead, Ph3SnH transfers H to substrates usually via a radical chain mechanism. This reactivity exploits the relatively good stability of "Ph3Sn·"〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Triphenyltin hydride」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.